Comark WT4 Bedienungsanleitung

Comark Lebensmittelthermometer WT4

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! Kerosene Spirit Filled Glass Thermometer

Safety Data Sheet

Effective date: April 1, 2016 According to 29 CFR 1910:1200 and GHS Rev. 3 Page 1 4 of !

SECTION 1: Identification of the substance/mixture and of the Manufacturer

Chemical Name: - -6) Kerosene (CAS No: 08008 20

Manufacturer Product Name: Kerosene Spirit Filled Glass Thermometer

Recommended uses of the chemical/product: Kerosene dyed with a red aniline dye is the thermometric fluid in a kerosene spirit filled

glass thermometer. The dyed expands or contracts with change in temperature. The thermometer will have approximately 2 cc kerosene

of kerosene.

Manufacturer Details: Emergency Telephone Number:

Miller-Weber of Texas -Chem Tel, Inc. (Contract Number: MIS0003159)

1- - - 6952 Lawndale Street 800 255 3924

Houston, TX 77023

- -713 926 2623 Fax: 713 926 7736- -

SECTION 2: Hazards Identification

The amount of kerosene cc. This section identifies the hazards of the substance, in a single thermometer is approximately two

without regard of amount of kerosene present in the finished product.

Hazard Classification of the chemical -(GHS US Hazard Pictograms):

GHS0 GHS0 GHS08 7 9

Signal word (GHS-US): Danger

Hazard statements (GHS US):- H 7 – 22 Combustible liquid.

H – 304 May be fatal if swallowed and enters airways

H – 315 Causes skin irritation

H411 – Toxic to aquatic life with long lasting effects.

Precautionary statements (GHS- US): – P210 Keep away from heat, sparks, open flames, hot surfaces. – No smoking

– P264 Wash skin, hands thoroughly after handling

– P273 Avoid release to the environment

– P280 Wear eye protection, protective clothing, protective gloves, face mask

– P301+P310 IF SWALLOWED: immediately call a POISON CENTER or doctor/physician

P302 - +P352 IF ON SKIN: Wash with plenty of soap and water.

P331 – If swallowed, do NOT induce vomiting

P332+P313 – If skin irritation occurs: Get medical advice/attention

P362 – Take off contaminated clothing and wash before reuse.

P370+P378 – - In case of fire: Use carbon dioxide (CO2), powder, alcohol resistant foam for extinction

P391 – Collect spillage.

5 - P403+P23 Store in a well- ventilated place. Keep cool.

- P405 Store locked up

– P501 Dispose of contents/container to comply with local, state and federal regulations

NFPA/HMIS Ratings (0- - :4) (Non GHS) 2 2 0 Health: , Flammability: , Reactivity: , PPG: See Section 8

SECTION 3: Composition/Information on Ingredients

Name

Product Identifier

GHS-US Classification

Kerosine

CAS No. 08008- -6 20

100

Flam. Liq. 4 7 , H22

Skin Irrit. 2, H315

Asp. Tox. 1, H304

Aquatic Chronic 2, H411

See Section 16 for full text of H- phrases

SECTION 4: First aid measures

The first aid measures described in this section are for exposure to kerosene kerosene, regardless of the quantity of the involved in the

exposure. The first aid measures below come from the Safety Data Sheets of our bulk kerosene suppliers.

Description of first aid measures

General: Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of dangerous area.

After inhalation: Move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

After skin contact: Wash off with soap and plenty of water. Consult a physician.

After eye contact: Flush eyes with water as a precaution.

After swallowing (ingestion): Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water.

Consult a physician.

Most important symptoms and effects, both acute and delayed: The most important known symptoms and effects are described in Section 2 and/or in

section 11.

Indication of any immediate medical attention and special treatment needed: No data available.

! Kerosene Spirit Filled Glass Thermometer

Safety Data Sheet

Effective date: April 1, 2016 According to 29 CFR 1910:1200 and GHS Rev. 3 Page 2 4 of !

SECTION 5: Firefighting measures

Extinguishing media

Suitable extinguishing agents: Use water spray, alcohol- resistant foam, dry chemical or carbon dioxide.

Unsuitable extinguishing media: None identified, but avoid heavy water stream.

Special hazards arising from the substance or mixture: Nature of decomposition products not known.

Advice to firefighters: Wear self-contained breathing apparatus for firefighting, if necessary.

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

General Measures: If thermometer breaks, wipe up liquid with disposable wiping cloth. Allow to dry under a fume hood and discard or discard

into spark and explosion proof waste receptacle.

Protective Equipment: See Section 8.

Emergency procedures: Keep upwind. Keep away from engines. No smoking. No flames or sparks. Wash contaminated clothing.

Environmental precautions Prevent leakage or spillage into drains and sewers. Discharge into the environment must be avoided.

Methods and material for containment and cleaning up Carefully clean up broken glass. Wipe up liquid kerosene spirit immediately after putting on

protective equipment.

Reference to other sections For disposal see section 13.

SECTION 7: Handling and storage

Precautions for safe handling

Handle and store thermometer in such a way to prevent breakage. If thermometer breaks will be released. Do not handle until all , kerosene

safety precautions have been read and understood. kin and eyes. Avoid inhalation of vapor or mist. Avoid contact with s Wash hands and other

exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in case of breakage.

Supply spark and explosion proof waste receptacle, as necessary.

Hygiene measures

Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Do not eat, drink or

smoke when using this product.

Conditions for safe storage, including any incompatibilities

Store thermometer in such a way to prevent breakage. Store away from direct sunlight, sources of intense heat, or where freezing is possible.

Store away from materials incompatible with kerosene secure kerosene (see Section 10 of this SDS). Store in area that will if thermometer is

broken in storage. Inspect all incoming containers with thermometers carefully for breakage. If breakage is suspected, use proper protective

equipment (see Section 8 of this SDS) and containment. Store and handle in well ventilated areas. .

SECTION 8: Exposure controls/personal protection

Control Parameters:

Kerosene (Kerosine) CAS No. 08008- -6 20

Remarks

USA

ACGIH

ACGIH TLV

200 mg/m3

Central Nervous System impairment; Upper Respiratory Tract irritation; Skin irritation; Application

restricted to conditions in which there are negligible aerosol exposures; Confirmed animal

carcinogen with unknown relevance to humans; Danger of cutaneous absorption varies.

USA

NIOSH

NIOSH TWA

100 mg/m3

A refined petroleum solvent (predominantly C9-C16), which typically is 25% normal paraffins, 11%

branched paraffins, 30% monocycloparaffins, 12% dicycloparaffins, 1% tricycloparaffins, 16%

monomuclear aromatics & 5% dinuclear aromatics.

Appropriate Engineering controls

Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure adequate

ventilation. Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of the workday.

Personal Protective Equipment (if thermometer breaks)

If thermometer breaks, avoid all unnecessary exposure. Gloves. Protective clothing. Safety glasses or goggles. Respiratory protection if

concentration in air is above the exposure limits .

Hand Protection: Handle with gloves. Nitrile rubber give good protection. Gloves must be inspected prior to use. Use proper glove removal

technique (without touching glove’s outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance

with applicable laws and good laboratory practices. Wash and dry hands.

Eye Protection: Safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as

NIOSH (US) Use a face shield if misting or large quantities of liquid splashing is expected..

Respiratory Protection: Where risk assessment shows air- - -purifying respirations are appropriate use a full face respirator with multi purpose

combination (US) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face

supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US).

Skin and Body Protection: Complete suit protecting against chemicals. The type of protective equipment must be selected according to the

concentration and amount of the dangerous substance at the specific workplace.

Control of environmental exposure: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the

environment must be avoided.

! Kerosene Spirit Filled Glass Thermometer

Safety Data Sheet

Effective date: April 1, 2016 According to 29 CFR 1910:1200 and GHS Rev. 3 Page 3 4 of !

SECTION 9: Physical and chemical properties

Appearance (physical state, color)

Red dyed liquid

Explosion Limit (upper/lower)

5% (V)/0.7% (V)

Odor

No data available

Vapor pressure

0.31 hPa at 20 °C

Odor threshold

No data available

Vapor density

No data available

pH value

No data available

Relative density

0.800 g/cm3 at 5 °C 1

Melting/Freezing point

No data available

Solubilities (at 25 °C)

No data available

Boiling point/ Boiling range

175 325 °C-

Partition coefficient (n- octanol/water)

No data available

Flash point

70 °C

Auto/Self- ignition temperature

No data available

Relative Evaporation rate (butylacetate=1)

No data available

Decomposition temperature

No data available

Flammability (solid, gaseous)

No data available

Viscosity

No data available

Upper/Lower flammability limits

5% (V)/ 0.7% (V)

Surface tension

32 mN/m at 20 °C

SECTION 10: Stability and reactivity

Reactivity: No data available.

Chemical stability: Stable under normal conditions of use. Stable under recommended storage conditions.

Possibility of hazardous reactions: No data available.

Conditions to avoid: Intact thermometer should not be exposed to hydrofluoric acid. Avoid Excessive heat, sources of ignition, direct sunlight and

extremely high or low temperatures. If broken, avoid materials incompatible with kerosene.

Incompatible materials: Strong oxidizing agents, strong bases, strong acids, amines.

Hazardous decomposition products: Other decomposition products- no data available. In the event of fire: see Section 5.

SECTION 11: Toxicological information

Acute toxicity: Not classified

Kerosene - -6 (Kerosine) CAS No. 08008 20

LD50 oral rat

2835 mg/kg Remarks: Behavioral: Muscle weakness. Lungs, Thorax, or Respiration: Respiratory stimulation. Endocrine:

Hypoglycemia.

dermal rabbit

Irritating to skin – 24 h (Draize Test). No other data available.

LD50 inhalation rat (mg/l)

No data available.

Skin corrosion/irritation: Irritating to skin.

Serious eye damage/irritation: No data available.

Respiratory or skin sensitization: No data available.

Germ cell mutagenicity: No data available.

Carcinogenicity: No component of this products present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human

carcinogen by IARC, NTP or OSHA.

Reproductive toxicity: No data available.

Specific target organ toxicity- (single exposure): Inhalation – Respiratory system.

Specific target organ toxicity (repeated exposure):- No data available.

Aspiration hazard: May be fatal if swallowed and enters airways.

Additional Information: RTECS: OA5500000. The supplier bulk chemical SDS explains to the best of their knowledge, the chemical, physical, and

toxicological properties have not been thoroughly investigated.

See Section 4 of the SDS for most important symptoms and effects, both acute and delayed for inhalation, skin contact, eye contact, ingestion

and chronic symptoms of kerosene exposure.

SECTION 12: Ecological information

Exotoxicity: No data available.

Persistence and degradability: No data available.

Bioaccumulative: No data available.

Mobility in soil ( - -6):Kerosene CAS No. 08008 20

Surface tension: m 32 N/m (20 °C)

Other adverse effects: An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Toxic to aquatic life with long

lasting effects.

SECTION 13: Disposal considerations

Waste disposal recommendations:

In bulk quantities, this combustible material may be burned in a chemical incinerator equipped with an afterburner and scrubber. Offer surplus and